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Synthesis and crystal structure of (E)-1,2-bis-[2-(methyl-sulfan-yl)phen-yl]diazene.

ABSTRACT: The title compound, C14H14N2S2, was obtained by transmetallation of 2,2'-bis-(tri-methyl-stann-yl)azo-benzene with methyl lithium, and subsequent quenching with dimethyl di-sulfide. The asymmetric unit comprises two half-mol-ecules, the other halves being completed by inversion symmetry at the midpoint of the azo group. The two mol-ecules show only slight differences with respect to N=N, S-N and aromatic C=C bonds or angles. Hirshfeld surface analysis reveals that except for one weak H?S inter-action, inter-molecular inter-actions are dominated by van der Waals forces only.

SUBMITTER: Hoffmann J

PROVIDER: S-EPMC6829741 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of (E)-1,2-bis-[2-(methyl-sulfan-yl)phen-yl]diazene.

Hoffmann Jonas J Kuczmera Thomas J TJ Lork Enno E Staubitz Anne A

Acta crystallographica. Section E, Crystallographic communications 20191031 Pt 11

The title compound, C14H14N2S2, was obtained by transmetallation of 2,2'-bis-(tri-methyl-stann-yl)azo-benzene with methyl lithium, and subsequent quenching with dimethyl di-sulfide. The asymmetric unit comprises two half-mol-ecules, the other halves being completed by inversion symmetry at the midpoint of the azo group. The two mol-ecules show only slight differences with respect to N=N, S-N and aromatic C=C bonds or angles. Hirshfeld surface analysis ...[more]

PMID: 31709113

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