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The Effect of Titanium Dioxide Surface Modification on the Dispersion, Morphology, and Mechanical Properties of Recycled PP/PET/TiO₂ PBNANOs.

ABSTRACT: Titanium dioxide (TiO₂) nanoparticles have recently appeared in PET waste because of the introduction of opaque PET bottles. We prepare polymer blend nanocomposites (PBNANOs) by adding hydrophilic (hphi), hydrophobic (hpho), and hydrophobically modified (hphoM) titanium dioxide (TiO₂) nanoparticles to 80rPP/20rPET recycled blends. Contact angle measurements show that the degree of hydrophilicity of TiO₂ decreases in the order hphi > hpho > hphoM. A reduction of rPET droplet size occurs with the addition of TiO₂ nanoparticles. The hydrophilic/hydrophobic balance controls the nanoparticles location. Transmission electron microscopy (TEM_ shows that hphi TiO₂ preferentially locates inside the PET droplets and hpho at both the interface and PP matrix. HphoM also locates within the PP matrix and at the interface, but large loadings (12%) can completely cover the surfaces of the droplets forming a physical barrier that avoids coalescence, leading to the formation of smaller droplets. A good correlation is found between the crystallization rate of PET (determined by DSC) and nanoparticles location, where hphi TiO₂ induces the highest PET crystallization rate. PET lamellar morphology (revealed by TEM) is also dependent on particle location. The mechanical behavior improves in the elastic regime with TiO₂ addition, but the plastic deformation of the material is limited and strongly depends on the type of TiO₂ employed.

SUBMITTER: Matxinandiarena E

PROVIDER: S-EPMC6835408 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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The Effect of Titanium Dioxide Surface Modification on the Dispersion, Morphology, and Mechanical Properties of Recycled PP/PET/TiO2 PBNANOs.

Matxinandiarena Eider E Múgica Agurtzane A Zubitur Manuela M Yus Cristina C Sebastián Víctor V Irusta Silvia S Loaeza Alfonso David AD Santana Orlando O Maspoch Maria Lluisa ML Puig Cristian C Müller Alejandro J AJ

Polymers 20191016 10

Titanium dioxide (TiO2) nanoparticles have recently appeared in PET waste because of the introduction of opaque PET bottles. We prepare polymer blend nanocomposites (PBNANOs) by adding hydrophilic (hphi), hydrophobic (hpho), and hydrophobically modified (hphoM) titanium dioxide (TiO2) nanoparticles to 80rPP/20rPET recycled blends. Contact angle measurements show that the degree of hydrophilicity of TiO2 decreases in the order hphi > hpho > hphoM. A reduction of r ...[more]

PMID: 31623120

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Project description:To alleviate the heavy burden on landfilling, construction and demolition wastes (C&DWs) are recycled and reused as aggregates in cementitious materials. However, the inherent characteristics of recycled fine aggregates (RFA), such as the high crushing index and high-water absorption, magnify the reusing difficulty. Nevertheless, attributing to the high porosity and high level of calcium hydroxides existing in the old mortar, RFA is featured with a high specific surface area and a high alkalinity. These features are useful to augment the total photo-degradation of SO2 by nano-TiO2 (NT) intermixed mortar, leading RFA to be an excellent potential carrier to load nano-TiO2 and prepare the composite photocatalyst. Hence, this study proposed to load NT onto the surface of RFAs and river sands (RSs) (the control) by the soaking method, preparing composite photocatalysts denoted as NT@RFA and NT@RS, respectively. The prepared composite photocatalysts were then utilized as sands in photocatalytic mortar to evaluate for SO2 degradation. Experiments identified a 50% higher amount of NT was loaded onto the surface of FRA relative to the control. This higher loading amount plus higher alkalinity ultimately translated into a higher photocatalytic activity. In addition, the mortar containing NT@RFA exhibited 46.3% higher physiochemical absorption and 23.9% higher photocatalytic activity than that containing NT@RS. In addition, the durability, embodied by the reuse and anti-abrasive properties, of NT@RFA exceeded that of NT@RS. The overall findings reveal that the NT@RFA not only garners beneficial effect from the high porosity but also generates positive effect from the high alkalinity. Though a number of studies deal with building materials with NT, this study is the first to load NT onto RFA and prepare composite photocatalysts which were then used as fine aggregates in building materials. Consequently, this study proves the potential high-added-value reusability of RFA in green construction materials and provides a low-cost, high-efficiency approach to degrade atmospheric SO2.

Dataset Information

The Effect of Titanium Dioxide Surface Modification on the Dispersion, Morphology, and Mechanical Properties of Recycled PP/PET/TiO₂ PBNANOs.

Publications

The Effect of Titanium Dioxide Surface Modification on the Dispersion, Morphology, and Mechanical Properties of Recycled PP/PET/TiO<sub>2</sub> PBNANOs.

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