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Rhodium(I) Pincer Complexes of Nitrous Oxide.

ABSTRACT: The synthesis of two well-defined rhodium(I) complexes of nitrous oxide (N2 O) is reported. These normally elusive adducts are stable in the solid state and persist in solution at ambient temperature, enabling comprehensive structural interrogation by 15 N NMR and IR spectroscopy, and single-crystal X-ray diffraction. These methods evidence coordination of N2 O through the terminal nitrogen atom in a linear fashion and are supplemented by a computational energy decomposition analysis, which provides further insights into the nature of the Rh-N2 O interaction.

SUBMITTER: Gyton MR

PROVIDER: S-EPMC6856677 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Rhodium(I) Pincer Complexes of Nitrous Oxide.

Gyton Matthew R MR Leforestier Baptiste B Chaplin Adrian B AB

Angewandte Chemie (International ed. in English) 20190912 43

The synthesis of two well-defined rhodium(I) complexes of nitrous oxide (N2 O) is reported. These normally elusive adducts are stable in the solid state and persist in solution at ambient temperature, enabling comprehensive structural interrogation by 15 N NMR and IR spectroscopy, and single-crystal X-ray diffraction. These methods evidence coordination of N2 O through the terminal nitrogen atom in a linear fashion and are supplemented by a computational energy d ...[more]

PMID: 31513331

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