Ontology highlight
ABSTRACT:
SUBMITTER: Hillenbrand J
PROVIDER: S-EPMC6856820 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20190917 44
A new type of molybdenum alkylidyne catalysts for alkyne metathesis is described, which is distinguished by an unconventional podand topology. These structurally well-defined complexes are easy to make on scale and proved to be tolerant toward numerous functional groups; even certain protic substituents were found to be compatible. The new catalysts were characterized by X-ray crystallography and by spectroscopic means, including <sup>95</sup> Mo NMR. ...[more]