Ontology highlight
ABSTRACT:
SUBMITTER: Du L
PROVIDER: S-EPMC6862224 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Du Lili L Yan Zhiping Z Bai Xueqin X Liang Runhui R Phillips David Lee DL
International journal of molecular sciences 20191105 21
Nitrenium ions are common reactive intermediates with high activities towards some biological nucleophiles. In this paper, we employed femtosecond transient absorption (fs-TA) and nanosecond transient absorption (ns-TA) as well as nanosecond time-resolved resonance Raman (ns-TR<sup>3</sup>) spectroscopy and density function theory (DFT) calculations to study the spectroscopic properties of the <i>N</i>(4,4'-dibromodiphenylamino)-2,4,6-trimethylpyridinium BF<sub>4</sub><sup>-</sup> salt (<b>1</b> ...[more]