Dataset Information

Improving the Performance of PVDF/PVDF-g-PEGMA Ultrafiltration Membranes by Partial Solvent Substitution with Green Solvent Dimethyl Sulfoxide during Fabrication.

ABSTRACT: Traditional organic solvents used in membrane manufacturing, such as dimethylformamide and tetrahydrofuran, are generally very hazardous and harmful to the environment and human health. Their total or partial substitution with green solvent dimethyl sulfoxide (DMSO) is proposed to fabricate membranes composed of poly(vinylidene fluoride) (PVDF) blended with PVDF-graft-poly(ethylene glycol) methyl ether methacrylate (PEGMA), with the purpose to accomplish a greener chemical process and enhance the membrane performance. Various organic solvent compositions were first investigated using the Hansen solubility theory, and the best mixture was thus applied experimentally. The membrane prepared by a ratio of N,N-dimethylacetamide/DMSO = 7:3 outperformed the membranes prepared by other solvent mixtures. This membrane showed high wetting behavior with the water contact angle declining from 71 to 7° in 18 s and a pure water flux reaching values larger than 700 L m-2 h-1 under 0.07 MPa applied hydraulic pressure. The membrane rejected sodium alginate at a rate of 87%, and nearly complete flux recovery was achieved following fouling and physical cleaning. The introduction of green chemistry concepts to PVDF/PVDF-g-PEGMA blended membranes is a step forward in the goal to increase the sustainability of membrane production.

SUBMITTER: Wu Q

PROVIDER: S-EPMC6882131 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Improving the Performance of PVDF/PVDF-<i>g</i>-PEGMA Ultrafiltration Membranes by Partial Solvent Substitution with Green Solvent Dimethyl Sulfoxide during Fabrication.

Wu Qidong Q Tiraferri Alberto A Wu Haibo H Xie Wancen W Liu Baicang B

ACS omega 20191107 22

Traditional organic solvents used in membrane manufacturing, such as dimethylformamide and tetrahydrofuran, are generally very hazardous and harmful to the environment and human health. Their total or partial substitution with green solvent dimethyl sulfoxide (DMSO) is proposed to fabricate membranes composed of poly(vinylidene fluoride) (PVDF) blended with PVDF-<i>graft</i>-poly(ethylene glycol) methyl ether methacrylate (PEGMA), with the purpose to accomplish a greener chemical process and enh ...[more]

PMID: 31788612

Similar Datasets

Project description:Dimethyl sulfoxide (DSMO) is a simple molecule widely used because of its great solvating ability, but this solvent also has little-known biological effects, especially on fungi. Aspergillus flavus is a notorious pathogenic fungus which may contaminate a large variety of crops worldwide by producing aflatoxins, endangering at the same time food safety and international trade. The aim of this study was to characterize the effect of DMSO on A. flavus including developmental parameters such as germination and sporulation, as well as its transcriptome profile using high-throughput RNA-sequencing assay and its impact on secondary metabolism (SM). After DMSO exposure, A. flavus displayed depigmented conidia in a dose-dependent manner. The four-day exposition of cultures to two doses of DMSO, chosen on the basis of depigmentation intensity (35 mM "low" and 282 mM "high"), led to no significant impact on fungal growth, germination or sporulation. However, transcriptomic data analysis showed that 4891 genes were differentially regulated in response to DMSO (46% of studied transcripts). A total of 4650 genes were specifically regulated in response to the highest dose of DMSO, while only 19 genes were modulated upon exposure to the lowest dose. Secondary metabolites clusters genes were widely affected by the DMSO, with 91% of clusters impacted at the highest dose. Among these, aflatoxins, cyclopiazonic acid and ustiloxin B clusters were totally under-expressed. The genes belonging to the AFB1 cluster were the most negatively modulated ones, the two doses leading to 63% and 100% inhibition of the AFB1 production, respectively. The SM analysis also showed the disappearance of ustiloxin B and a 10-fold reduction of cyclopiazonic acid level when A. flavus was treated by the higher DMSO dose. In conclusion, the present study showed that DMSO impacted widely A. flavus' transcriptome, including secondary metabolism gene clusters with the aflatoxins at the head of down-regulated ones. The solvent also inhibits conidial pigmentation, which could illustrate common regulatory mechanisms between aflatoxins and fungal pigment pathways. Because of its effect on major metabolites synthesis, DMSO should not be used as solvent especially in studies testing anti-aflatoxinogenic compounds.

Dataset Information

Improving the Performance of PVDF/PVDF-g-PEGMA Ultrafiltration Membranes by Partial Solvent Substitution with Green Solvent Dimethyl Sulfoxide during Fabrication.

Publications

Improving the Performance of PVDF/PVDF-<i>g</i>-PEGMA Ultrafiltration Membranes by Partial Solvent Substitution with Green Solvent Dimethyl Sulfoxide during Fabrication.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets