Ontology highlight
ABSTRACT:
SUBMITTER: Hong DH
PROVIDER: S-EPMC6884086 | biostudies-literature | 2019 Apr
REPOSITORIES: biostudies-literature
Hong Dae Ho DH Murray Leslie J LJ
European journal of inorganic chemistry 20190129 15
The reduction of CO<sub>2</sub> to formic acid by transition metal hydrides is a potential pathway to access reactive C1 compounds. To date, no kinetic study has been reported for insertion of a bridging hydride in a weak-field ligated complex into CO<sub>2</sub>; such centers have relevance to metalloenzymes that catalyze this reaction. Herein, we report the kinetic study of the reaction of a tri(<i>μ</i>-hydride)triiron(II/II/II) cluster supported by a tris(β-diketimine) cyclophane (<b>1</b>) ...[more]