Dataset Information

Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry.

ABSTRACT: In this study, a useful analytical method was developed and validated for measuring the residues of dimethyl disulphide (DMDS) in cucumbers and soil by gas chromatography-tandem mass spectrometry (GC-MS/MS). The dissipation dynamics and residual levels of DMDS in cucumber and soil were also studied in Shandong, Jilin, and Hebei provinces by using this method. Dichloromethane was selected and used as the extraction solvent to extract the target pesticide from the soil and cucumber samples. The soil and cucumber samples were cleaned up by the combination of multiwalled carbon nanotubes (MWCNT) and biochar. The average recoveries of the DMDS in cucumbers and soil were in the range of 84-101.5%, with relative standard deviations (RSD) of 0.7-4.9%, when they spiked at 0.05, 0.5, and 5 mg/kg DMDS respectively. The limit of quantification (LOQ) of this method was 0.05 mg/kg. First-order and second-order kinetic equations were used to fit dissipation data. Results show that the half-lives of DMDS in the soil at Shandong, Jilin, and Hebei were 1.63-4.47 days, 1.96-6.49 days, and 1.35-2.51 days, respectively. The final residues of DMDS were less than 0.05 mg/kg in cucumbers and 0.36 mg/kg in the soil. The dissipation rates of DMDS in different soils were different. The method provides a basis for the risk assessment of DMDS in cucumber and soil.

SUBMITTER: Kaium A

PROVIDER: S-EPMC6888082 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry.

Kaium Abdul A Cao Junli J Liu Xingang X Xu Jun J Dong Fengshou F Wu Xiaohu X Zheng Yongquan Y

International journal of environmental research and public health 20191114 22

In this study, a useful analytical method was developed and validated for measuring the residues of dimethyl disulphide (DMDS) in cucumbers and soil by gas chromatography-tandem mass spectrometry (GC-MS/MS). The dissipation dynamics and residual levels of DMDS in cucumber and soil were also studied in Shandong, Jilin, and Hebei provinces by using this method. Dichloromethane was selected and used as the extraction solvent to extract the target pesticide from the soil and cucumber samples. The so ...[more]

PMID: 31739625

Similar Datasets

Project description:Nitromethane is a volatile organic compound categorized as a Group 2B carcinogen by the International Agency for Research on Cancer. It has been detected in mainstream cigarette smoke, but few reliable methods have been reported for accurate quantification. We developed, a sensitive, selective, fully validated method for the targeted determination of nitromethane in mainstream tobacco smoke in ten U.S. domestic brands and two quality control materials (3R4F and CM6). The vapor phase portion of machine-generated cigarette mainstream smoke, under modified ISO 3308:2000 regime (ISO) and modified intense regime (HCI), from single cigarettes was collected using airtight polyvinylfluoride sampling bags. The bags' contents were extracted using methanol containing an isotopically labeled internal standard followed by gas chromatography-tandem mass spectrometry. This approach is sufficiently sensitive to measure nitromethane levels in the nanogram range, with a method limit of detection of 72.3 ng/cig. Within-product variability estimated from the replicate analysis of 10 products ranged from 4.6%-16.3% (n = 6) over the two different smoking regimes, and method reproducibility estimated from two products used as quality control materials (3R4F and CM6) yielded intermediate precision values ranging from 16.6 to 20.8% (n = 20). Under HCI, nitromethane yields in machine-generated cigarette smoke from ten different domestic cigarette products ranged from 3.2 to 12 μg/cig; under ISO yields ranged from 1.6 to 4.9 μg/cig under standardized smoking machine conditions. Nitromethane yields are related to both the smoke regime (blocking of vent holes, puff duration and puff volume) and the heterogeneity of tobacco mixtures. This method provides a selective and fully validated technique to accurately quantify nitromethane in mainstream cigarette smoke, with minimal waste generation. It is an improvement over previous methods with regards to specificity, throughput, and simplicity of the sample collection process.

Dataset Information

Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry.

Publications

Method Validation and Dissipation Behaviour of Dimethyl Disulphide (DMDS) in Cucumber and Soil by Gas Chromatography-Tandem Mass Spectrometry.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets