Ontology highlight
ABSTRACT:
SUBMITTER: Han T
PROVIDER: S-EPMC6889291 | biostudies-literature | 2019 Dec
REPOSITORIES: biostudies-literature
Han Ting T Han Ting T Yao Zhanshi Z Qiu Zijie Z Zhao Zheng Z Wu Kaiyi K Wang Jianguo J Poon Andrew W AW Lam Jacky W Y JWY Tang Ben Zhong BZ
Nature communications 20191202 1
The development of facile and efficient polymerizations toward functional polymers with unique structures and attractive properties is of great academic and industrial significance. Here we develop a straightforward C-H-activated polyspiroannulation route to in situ generate photoresponsive spiro-polymers with complex structures. The palladium(II)-catalyzed stepwise polyspiroannulations of free naphthols and internal diynes proceed efficiently in dimethylsulfoxide at 120 °C without the constrain ...[more]