Unknown

Dataset Information

0

Pd/MCM-41 catalyst for acetylene hydrogenation to ethylene.


ABSTRACT: This study aims to produce ethylene using the calcium carbide route, acetylene from calcium carbide and then selective hydrogenation of the high-concentration acetylene to ethylene. A series of catalysts with different supports, such as Al2O3, SiO2 and MCM-41, were prepared using the ethylene glycol reduction method and their catalytic properties for high-concentration acetylene hydrogenation of calcium carbide to ethylene were studied by transmission electron microscopy, X-ray powder diffraction and thermogravimetry, among others. The results show that the small particle size and uniform dispersion of palladium (Pd) particles in the Pd/MCM-41 catalyst produced the highest ethylene yield of 62.09%. Then, the conditions for the basic reaction, such as reaction temperature and space velocity, were optimized using MCM-41 as a support. The yield of ethylene after condition optimization was as high as 82.87%, while the loading of Pd was 0.1%.

SUBMITTER: Kang L 

PROVIDER: S-EPMC6894548 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6083668 | biostudies-literature
| S-EPMC8005196 | biostudies-literature
| S-EPMC7876846 | biostudies-literature
| S-EPMC5513583 | biostudies-literature
| S-EPMC7663855 | biostudies-literature
| S-EPMC11367406 | biostudies-literature
| S-EPMC6669689 | biostudies-literature
| S-EPMC7675534 | biostudies-literature
| S-EPMC8446008 | biostudies-literature
| S-EPMC6387010 | biostudies-literature