Ontology highlight
ABSTRACT:
SUBMITTER: Chen B
PROVIDER: S-EPMC6899814 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Chen Bin B Horiuchi Shinnosuke S Holstein Julian J JJ Tessarolo Jacopo J Clever Guido H GH
Chemistry (Weinheim an der Bergstrasse, Germany) 20191024 65
For metal-mediated host compounds, the development of strategies to reduce symmetry and introduce multiple functionalities in a non-statistical way is a challenging task. We show that the introduction of steric stress around the coordination environment of square-planar Pd<sup>II</sup> cations and bis-monodentate nitrogen donor ligands allows to control the size and shape of the assembled product, from [Pd<sub>2</sub> L<sub>4</sub> ] cages over [Pd<sub>2</sub> L<sub>3</sub> ] bowl-shaped structu ...[more]