Transition-Metal Chemistry of Alkaline-Earth Elements: The Trisbenzene Complexes M(Bz)₃ (M=Sr, Ba).

ABSTRACT: We report the synthesis and spectroscopic identification of the trisbenzene complexes of strontium and barium M(Bz)₃ (M=Sr, Ba) in low-temperature Ne matrix. Both complexes are characterized by a D₃ symmetric structure involving three equivalent ?⁶ -bound benzene ligands and a closed-shell singlet electronic ground state. The analysis of the electronic structure shows that the complexes exhibit metal-ligand bonds that are typical for transition metal compounds. The chemical bonds can be explained in terms of weak donation from the ? MOs of benzene ligands into the vacant (n-1)d AOs of M and strong backdonation from the occupied (n-1)d AO of M into vacant ?* MOs of benzene ligands. The metals in these 20-electron complexes have 18 effective valence electrons, and, thus, fulfill the 18-electron rule if only the metal-ligand bonding electrons are counted. The results suggest that the heavier alkaline earth atoms exhibit the full bonding scenario of transition metals.

SUBMITTER: Wang Q 

PROVIDER: S-EPMC6900055 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature