Ontology highlight
ABSTRACT:
SUBMITTER: Vanicek S
PROVIDER: S-EPMC6914379 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Vanicek Stefan S Beerhues Julia J Bens Tobias T Levchenko Volodymyr V Wurst Klaus K Bildstein Benno B Tilset Mats M Sarkar Biprajit B
Organometallics 20191112 22
A gold(III) complex with the hitherto most electron poor mesoionic carbene ligand is presented. Aqua regia was the oxidizing agent of choice for the synthesis of this unusual organometallic compound. The Au<sup>III</sup> complex is redox-rich, and also acts as a catalyst for oxazole formation, delivering selectively a completely different isomer compared to its Au<sup>I</sup> congener. ...[more]