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ABSTRACT:
SUBMITTER: Dhara D
PROVIDER: S-EPMC6916326 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Dhara Debabrata D Das Shubhajit S Pati Swapan K SK Scheschkewitz David D Chandrasekhar Vadapalli V Jana Anukul A
Angewandte Chemie (International ed. in English) 20190912 43
An NHC-coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon-soluble monomeric Au<sup>I</sup> hydride, which readily adds CO<sub>2</sub> at room temperature yielding the corresponding Au<sup>I</sup> formate. The reversible reaction can be expedited by the addition of NHC, which induces β-hydride shift and the removal of CO<sub>2</sub> from equilibrium through the formation of an NHC-CO<sub>2</sub> adduct. The Au<sup>I</sup> formate is alternatively formed by dehydrogen ...[more]