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Binary Lead Fluoride Pb3 F8.


ABSTRACT: The binary lead fluoride Pb3 F8 was synthesized by the reaction of anhydrous HF with Pb3 O4 or by the reaction of BrF3 with PbF2 . The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS 19 F?NMR spectroscopy, as well as thermogravimetric analysis, XP and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Solid-state quantum-chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound.

SUBMITTER: Deubner HL 

PROVIDER: S-EPMC6916602 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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The binary lead fluoride Pb<sub>3</sub> F<sub>8</sub> was synthesized by the reaction of anhydrous HF with Pb<sub>3</sub> O<sub>4</sub> or by the reaction of BrF<sub>3</sub> with PbF<sub>2</sub> . The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS <sup>19</sup> F NMR spectroscopy, as well as thermogravimetric analysis, XP and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Solid-state quantum-chemical calculations are pr  ...[more]

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