Ontology highlight
ABSTRACT:
SUBMITTER: Deubner HL
PROVIDER: S-EPMC6916602 | biostudies-literature | 2019 Dec
REPOSITORIES: biostudies-literature
Deubner H Lars HL Sachs Malte M Bandemehr Jascha J Ivlev Sergei I SI Karttunen Antti J AJ Kachel Stefan R SR Klein Benedikt P BP Ruppenthal Lukas L Schöniger Maik M Krug Claudio K CK Herritsch Jan J Gottfried J Michael JM Aman Jamal N M JNM Schmedt Auf der Günne Jörn J Kraus Florian F
Chemistry (Weinheim an der Bergstrasse, Germany) 20191104 68
The binary lead fluoride Pb<sub>3</sub> F<sub>8</sub> was synthesized by the reaction of anhydrous HF with Pb<sub>3</sub> O<sub>4</sub> or by the reaction of BrF<sub>3</sub> with PbF<sub>2</sub> . The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS <sup>19</sup> F NMR spectroscopy, as well as thermogravimetric analysis, XP and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Solid-state quantum-chemical calculations are pr ...[more]