Nanoscaled Lithium Powders with Protection of Ionic Liquid for Highly Stable Rechargeable Lithium Metal Batteries.

ABSTRACT: To suppress the dendrite formation and alleviate volume expansion upon striping/platting is a key challenge for developing practical lithium metal anodes. Lithium metal in powder form possesses great potential to address this issue due to large specific surface area. However, the fabrication of powdery metallic lithium is largely restricted because of its unique softness, stickiness, and high reactivity. Here, a safe and readily accessible cryomilling process toward lithium powders is reported. Nanoscaled lithium powders (<500 nm) are successfully prepared from lithium foils with the assistance of a high-melting-point ionic liquid under cryogenic temperature. The prepared lithium powder anode exhibits superior electrochemical properties in symmetric cells, including extraordinarily low yet

SUBMITTER: Pu K 

PROVIDER: S-EPMC6918098 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature