Dataset Information

Facile Fabrication of C-TiO₂ Nanocomposites with Enhanced Photocatalytic Activity for Degradation of Tetracycline.

ABSTRACT: Visible-lightdriven C-TiO₂ nanocomposites were prepared via a simple calcination and acid etching process. The C-TiO₂ nanocomposites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and high-resolution TEM. The results showed that TiO₂ nanoparticles were combined with a porous carbon layer through surface C-O groups, which facilitates the strong interface interaction. The interface combination of nano-TiO₂ and carbon material increases the specific surface area of nano-TiO₂, widens the range of light response, and improves the efficiency of light-induced electron migration. The visible-light photocatalytic activity of the prepared photocatalyst was evaluated by the decomposition of tetracycline aqueous solution. Compared with that of pure TiO₂, the photocatalytic activity of C-TiO₂ nanocomposites was significantly improved. Furthermore, a possible photocatalytic mechanism was also tentatively proposed. This work can promote the development of active photocatalysts under solar light for the photodegradation of environmental pollutants.

SUBMITTER: Ma S

PROVIDER: S-EPMC6921265 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Facile Fabrication of C-TiO2 Nanocomposites with Enhanced Photocatalytic Activity for Degradation of Tetracycline.

Ma Shuaishuai S Gu Jiandong J Han Yingxia Y Gao Yuan Y Zong Yuqing Y Ye Zhaolian Z Xue Jinjuan J

ACS omega 20191203 25

Visible-lightdriven C-TiO2 nanocomposites were prepared via a simple calcination and acid etching process. The C-TiO2 nanocomposites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and high-resolution TEM. The results showed that TiO2 nanoparticles were combined with a porous carbon layer through surface C-O groups, which facilitates the strong interface interaction. The interface co ...[more]

PMID: 31867498

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Project description:Perfluorooctanoic acid (PFOA), a typical perfluorinated carboxylic acid, is an emerging type of permanent organic pollutants that are regulated by the Stockholm Convention. The degradation of PFOA, however, is quite challenging largely due to the ultra-high stability of C-F bonds. Compared with other techniques, photocatalytic degradation offers the potential advantages of simple operation under mild conditions as well as exceptional decomposition and defluorination efficiency. Titanium dioxide (TiO2) is one of the most frequently used photocatalysts, but so far, the pristine nanosized TiO2 (e.g., the commercial P25) has been considered inefficient for PFOA degradation, since the photo-generated hydroxyl radicals from TiO2 are not able to directly attack C-F bonds. Mesoporous Sb2O3/TiO2 heterojunctions were therefore rationally designed in this work, of which the confined Sb2O3 nanoparticles in mesoporous TiO2 framework could not only tune the band structure and also increase the number of active sites for PFOA degradation. It was found that, after loading Sb2O3, the absorption of UV light was enhanced, indicating a higher efficiency of light utilization; while the band gap was reduced, which accelerated the separation of photo-generated charge carriers; and most importantly, the valence band edge of the Sb2O3/TiO2 heterojunction was significantly lifted so as to prevent the occurrence of hydroxyl radical pathway. Under the optimal ratio of Sb2O3-TiO2, the resulting catalysts managed to remove 81.7% PFOA in 2 h, with a degradation kinetics 4.2 times faster than the commercial P25. Scavenger tests and electron spin resonance spectra further revealed that such improvement was mainly attributed to the formation of superoxide radicals and photo-generated holes, in which the former drove the decarboxylation from C7F15COOH-C7F15 •, and the latter promoted the direct electron transfer for the conversion of C7F15COO--C7F15COO•. The Sb2O3/TiO2 photocatalysts were highly recyclable, with nearly 90% of the initial activity being retained after five consecutive cycles, guaranteeing the feasibility of long-term operation.

Dataset Information

Facile Fabrication of C-TiO₂ Nanocomposites with Enhanced Photocatalytic Activity for Degradation of Tetracycline.

Publications

Facile Fabrication of C-TiO<sub>2</sub> Nanocomposites with Enhanced Photocatalytic Activity for Degradation of Tetracycline.

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