Dataset Information

Synthesis and Photoluminescence of Tetracyanidonitridorhenium(V) Complexes with Five-Membered N-Heteroaromatic Ligands and Photoluminescence-Intensity Change.

ABSTRACT: Novel tetracyanidonitridorhenium(V) complexes with five-membered N-heteroaromatic ligands, (PPh₄)₂[ReN(CN)₄L] [L = imidazole (Him) (2), 1-methylimidazole (Mim) (3), and pyrazole (pyz) (4)] and (PPh₄)₂[ReN(CN)₄L]·L [L = Him (5) and Mim (6)], were synthesized by the reactions of (PPh₄)₂[ReN(CN)₄] (1) with Him, Mim, and pyz, and their structures were determined by single-crystal X-ray analysis. The complexes 2, 3, 4, and 6 showed intense photoluminescence, with the emission quantum yields (?_em) being 0.65-0.75 in the solid state at 296 K. In contrast, the ?_em and ?_em values of 5 are significantly smaller and shorter, respectively, than the relevant values of 2. The interconversion reactions among 1, 2, and 5 accompanied by large photoluminescence-intensity changes were accomplished by solvent-free reactions and exposure of water. The mechanochemical reaction of 2 with 1 mol equiv of Him in the solid state gave 5. Complex 5 was also obtained by the mechanochemical reaction of 1 with 2 mol equivalents of Him in the solid state. By placing solid of 5 in water, the solid showed intense photoluminescence to give 2. Complex 1 was produced under vacuum at 185 °C from 2 or 5.

SUBMITTER: Seike M

PROVIDER: S-EPMC6921682 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Synthesis and Photoluminescence of Tetracyanidonitridorhenium(V) Complexes with Five-Membered N-Heteroaromatic Ligands and Photoluminescence-Intensity Change.

Seike Moe M Nagata Kojiro K Ikeda Hayato H Ito Akitaka A Sakuda Eri E Kitamura Noboru N Shinohara Atsushi A Yoshimura Takashi T

ACS omega 20191104 25

Novel tetracyanidonitridorhenium(V) complexes with five-membered N-heteroaromatic ligands, (PPh4)2[ReN(CN)4L] [L = imidazole (Him) (2), 1-methylimidazole (Mim) (3), and pyrazole (pyz) (4)] and (PPh4)2[ReN(CN)4L]·L [L = Him (5) and Mim (6)], were synthesized by the reactions of (PPh4)2[ReN(CN)4] (1) with Him, Mim, and pyz, and their structures were determine ...[more]

PMID: 31867519

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Dataset Information

Synthesis and Photoluminescence of Tetracyanidonitridorhenium(V) Complexes with Five-Membered N-Heteroaromatic Ligands and Photoluminescence-Intensity Change.

Publications

Synthesis and Photoluminescence of Tetracyanidonitridorhenium(V) Complexes with Five-Membered N-Heteroaromatic Ligands and Photoluminescence-Intensity Change.

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