Ontology highlight
ABSTRACT:
SUBMITTER: Donner A
PROVIDER: S-EPMC6921685 | biostudies-literature | 2019 Dec
REPOSITORIES: biostudies-literature
Donner Adrian A Trepka Bastian B Theiss Sebastian S Immler Fabian F Traber Johanna J Polarz Sebastian S
Langmuir : the ACS journal of surfaces and colloids 20191118 50
Next-generation surfactants provide extended functionality apart from their amphiphilic properties. We present two novel metallosurfactants characterized by an N-heterocyclic carbene (NHC) head bearing Cu(I) and Fe(II). An innovative approach for their application in emulsion polymerizations under atom transfer radical polymerization (ATRP) conditions was developed. Thereby the complexes fulfilled the role of emulsifiers, active catalysts, and stabilization agents at once. Polymerization of meth ...[more]