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Synthesis and Characterization of Unsymmetrical Double-Decker Siloxane (Basket Cage).

ABSTRACT: The one-pot synthesis of an unsymmetrical double-decker siloxane with a novel structure via the reaction of double-decker tetrasodiumsilanolate with 1 equiv. of dichlorotetraphenyldisiloxane in the presence of an acid is reported herein for the first time. The target compound bearing all phenyl substituents on the unsymmetrical siloxane structure was successfully obtained, as confirmed by 1H-NMR, 13C-NMR, 29Si-NMR, IR, MALDI-TOF, and X-ray crystallography analyses. Additionally, the thermal properties of the product were evaluated by TG/DTA and compared with those of other siloxane cage compounds.

SUBMITTER: Kunthom R

PROVIDER: S-EPMC6930635 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Synthesis and Characterization of Unsymmetrical Double-Decker Siloxane (Basket Cage).

Kunthom Rungthip R Takeda Nobuhiro N Unno Masafumi M

Molecules (Basel, Switzerland) 20191122 23

The one-pot synthesis of an unsymmetrical double-decker siloxane with a novel structure via the reaction of double-decker tetrasodiumsilanolate with 1 equiv. of dichlorotetraphenyldisiloxane in the presence of an acid is reported herein for the first time. The target compound bearing all phenyl substituents on the unsymmetrical siloxane structure was successfully obtained, as confirmed by 1H-NMR, 13C-NMR, 29Si-NMR, IR, MALDI-TOF, and X-ray crystallography analyse ...[more]

PMID: 31766625

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