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Atomic-Scale Identification of the Electrochemical Roughening of Platinum.

ABSTRACT: Electrode degradation under oxidizing conditions is a major drawback for large-scale applications of platinum electrocatalysts. Subjecting Pt(111) to oxidation-reduction cycles is known to lead to the growth of nanoislands. We study this phenomenon using a combination of simultaneous in situ electrochemical scanning tunneling microscopy and cyclic voltammetry. Here, we present a detailed analysis of the formed islands, deriving the (evolution of the) average island growth shape. From the island shapes, we determine the densities of atomic-scale defect sites, e.g., steps and facets, which show an excellent correlation with the different voltammetric hydrogen adsorption peaks. Based on this combination of electrochemical scanning tunneling microscopy (EC-STM) and CV data, we derive a detailed atomistic picture of the nanoisland evolution during potential cycling, delivering new insights into the initial stages of platinum electrode degradation.

SUBMITTER: Jacobse L

PROVIDER: S-EPMC6935890 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Atomic-Scale Identification of the Electrochemical Roughening of Platinum.

Jacobse Leon L Rost Marcel J MJ Koper Marc T M MTM

ACS central science 20191115 12

Electrode degradation under oxidizing conditions is a major drawback for large-scale applications of platinum electrocatalysts. Subjecting Pt(111) to oxidation-reduction cycles is known to lead to the growth of nanoislands. We study this phenomenon using a combination of simultaneous <i>in situ</i> electrochemical scanning tunneling microscopy and cyclic voltammetry. Here, we present a detailed analysis of the formed islands, deriving the (evolution of the) average island growth shape. From the ...[more]

PMID: 31893221

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