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Solid-State Chemiresistors from Two-Dimensional MoS2 Nanosheets Functionalized with l-Cysteine for In-Line Sensing of Part-Per-Billion Cd2+ Ions in Drinking Water.

ABSTRACT: Sensing of metal contaminants at ultralow concentrations in aqueous environments is vital in today's overpopulated world, with an extremely stringent limit (<5 ppb) for Cd2+ ions in drinking water. Here, we utilize sonochemically exfoliated molybdenum disulfide (MoS2) nanosheets functionalized with l-cysteine (Cys) as highly sensitive and selective two-dimensional (2D) materials for solid-state chemiresistors. We specifically targeted Cd2+ ions due to their high toxicity at low concentrations. MoS2-Cys nanosheets are fabricated using an ad hoc, low-complexity, one-pot synthesis method. Porous MoS2-Cys thin films with a high surface area are assembled from these nanosheets. Two-terminal chemiresistors incorporating MoS2-Cys films are demonstrated to be preferentially sensitive to Cd2+ ions at neutral pH, irrespective of other metal ions present in water flowing through the device. A 5 ppb concentration of the Cd2+ ions in the water stream increases the device resistivity by 20 times. Our devices operate at broad (1-500 ppb) range and fast (?1 s) response times. Cd2+ is selectively detected because of preferential, size-driven adsorption at the interstitials between l-cysteine functional groups, combined with pH-controlled charge transfer that removes electronic gap states from MoS2. MoS2-Cys-based chemiresistors can be deployed in-line to detect metal ions without any need for additional offline measurements.

SUBMITTER: Bazylewski P

PROVIDER: S-EPMC6964307 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Solid-State Chemiresistors from Two-Dimensional MoS2 Nanosheets Functionalized with l-Cysteine for In-Line Sensing of Part-Per-Billion Cd2+ Ions in Drinking Water.

Bazylewski Paul P Van Middelkoop Sheldon S Divigalpitiya Ranjith R Fanchini Giovanni G

ACS omega 20191226 1

Sensing of metal contaminants at ultralow concentrations in aqueous environments is vital in today's overpopulated world, with an extremely stringent limit (<5 ppb) for Cd2+ ions in drinking water. Here, we utilize sonochemically exfoliated molybdenum disulfide (MoS2) nanosheets functionalized with l-cysteine (Cys) as highly sensitive and selective two-dimensional (2D) materials for solid-state chemiresistors. We specifically targeted Cd2+ ions due to their high ...[more]

PMID: 31956813

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Project description:The capture of transient scenes at high imaging speed has been long sought by photographers, with early examples being the well known recording in 1878 of a horse in motion and the 1887 photograph of a supersonic bullet. However, not until the late twentieth century were breakthroughs achieved in demonstrating ultrahigh-speed imaging (more than 10(5) frames per second). In particular, the introduction of electronic imaging sensors based on the charge-coupled device (CCD) or complementary metal-oxide-semiconductor (CMOS) technology revolutionized high-speed photography, enabling acquisition rates of up to 10(7) frames per second. Despite these sensors' widespread impact, further increasing frame rates using CCD or CMOS technology is fundamentally limited by their on-chip storage and electronic readout speed. Here we demonstrate a two-dimensional dynamic imaging technique, compressed ultrafast photography (CUP), which can capture non-repetitive time-evolving events at up to 10(11) frames per second. Compared with existing ultrafast imaging techniques, CUP has the prominent advantage of measuring an x-y-t (x, y, spatial coordinates; t, time) scene with a single camera snapshot, thereby allowing observation of transient events with temporal resolution as tens of picoseconds. Furthermore, akin to traditional photography, CUP is receive-only, and so does not need the specialized active illumination required by other single-shot ultrafast imagers. As a result, CUP can image a variety of luminescent--such as fluorescent or bioluminescent--objects. Using CUP, we visualize four fundamental physical phenomena with single laser shots only: laser pulse reflection and refraction, photon racing in two media, and faster-than-light propagation of non-information (that is, motion that appears faster than the speed of light but cannot convey information). Given CUP's capability, we expect it to find widespread applications in both fundamental and applied sciences, including biomedical research.

Dataset Information

Solid-State Chemiresistors from Two-Dimensional MoS2 Nanosheets Functionalized with l-Cysteine for In-Line Sensing of Part-Per-Billion Cd2+ Ions in Drinking Water.

Publications

Solid-State Chemiresistors from Two-Dimensional MoS<sub>2</sub> Nanosheets Functionalized with l-Cysteine for In-Line Sensing of Part-Per-Billion Cd<sup>2+</sup> Ions in Drinking Water.

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