Accelerated Photo-Induced Degradation of Benzidine-p-Aminothiophenolate Immobilized at Light-Enhancing TiO₂ Nanotube Electrodes.

ABSTRACT: Herein, the enhanced visible-light-induced degradation of the azo-dye benzidine-p-aminothiophenolate immobilized on TiO₂ nanotube electrodes is reported. Exploiting the reported photonic properties of the TiO₂ support and the strong electronic absorption of the dye allowed for employing surface-enhanced resonance Raman spectroscopy at 413?nm to simultaneously trigger the photoreaction and follow the time-dependent decay process. Degradation rate constants of up to 25?s^-1 were observed, which stand among the highest reported values for laser-induced degradation of immobilized dyes on photonically active supports. Contrast experiments with two differently light-enhancing TiO₂ nanotube electrodes establish the direct correlation of the material's optical response, that is, electromagnetic field enhancement, on the interfacial photocatalytic reaction.

SUBMITTER: Querebillo CJ 

PROVIDER: S-EPMC6972621 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature