Role of the Iodide-Methylammonium Interaction in the Ferroelectricity of CH₃ NH₃ PbI₃.

ABSTRACT: Excellent conversion efficiencies of over 20?% and facile cell production have placed hybrid perovskites at the forefront of novel solar cell materials, with CH₃ NH₃ PbI₃ being an archetypal compound. The question why CH₃ NH₃ PbI₃ has such extraordinary characteristics, particularly a very efficient power conversion from absorbed light to electrical power, is hotly debated, with ferroelectricity being a promising candidate. This does, however, require the crystal structure to be non-centrosymmetric and we herein present crystallographic evidence as to how the symmetry breaking occurs on a crystallographic and, therefore, long-range level. Although the molecular cation CH₃ NH₃ ⁺ is intrinsically polar, it is heavily disordered and this cannot be the sole reason for the ferroelectricity. We show that it, nonetheless, plays an important role, as it distorts the neighboring iodide positions from their centrosymmetric positions.

SUBMITTER: Breternitz J 

PROVIDER: S-EPMC6972664 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature