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Porous g-C3N4 and MXene Dual-Confined FeOOH Quantum Dots for Superior Energy Storage in an Ionic Liquid.

ABSTRACT: Owing to their unique nanosize effect and surface effect, pseudocapacitive quantum dots (QDs) hold considerable potential for high-efficiency supercapacitors (SCs). However, their pseudocapacitive behavior is exploited in aqueous electrolytes with narrow potential windows, thereby leading to a low energy density of the SCs. Here, a film electrode based on dual-confined FeOOH QDs (FQDs) with superior pseudocapacitive behavior in a high-voltage ionic liquid (IL) electrolyte is put forward. In such a film electrode, FQDs are steadily dual-confined in a 2D heterogeneous nanospace supported by graphite carbon nitride (g-C3N4) and Ti-MXene (Ti3C2). Probing of potential-driven ion accumulation elucidates that strong adsorption occurs between the IL cation and the electrode surface with abundant active sites, providing sufficient redox reaction of FQDs in the film electrode. Furthermore, porous g-C3N4 and conductive Ti3C2 act as ion-accessible channels and charge-transfer pathways, respectively, endowing the FQDs-based film electrode with favorable electrochemical kinetics in the IL electrolyte. A high-voltage flexible SC (FSC) based on an ionogel electrolyte is fabricated, exhibiting a high energy density (77.12 mWh cm-3), a high power density, a remarkable rate capability, and long-term durability. Such an FSC can also be charged by harvesting sustainable energy and can effectively power various wearable and portable electronics.

SUBMITTER: Shi M

PROVIDER: S-EPMC6974951 | biostudies-literature |

REPOSITORIES: biostudies-literature

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White Photoluminescent Ti3C2 MXene Quantum Dots with Two-Photon Fluorescence.

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2019-05-31 | GSE89756 | GEO

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Project description:The metal halide with a perovskite structure has attracted significant attention due to its defect-tolerant photophysics and optoelectronic features. In particular, the all-inorganic metal halide perovskite quantum dots have potential for development in future applications. Sub-2 nm CsPbX3 (X = Cl, Br, and I) perovskite quantum dots were successfully fabricated by a MOF-confined strategy with a facile and simple route. The highly uniform microporous structure of MOF effectively restricted the CsPbX3 quantum dots aggregation in a synthetic process and endowed the obtained sub-2 nm CsPbX3 quantum dots with well-dispersed and excellent stability in ambient air without a capping agent. The photoluminescence emission spectra and lifetimes were not decayed after 60 days. The CsPbX3 quantum dots maintained size distribution stability in the air without any treatment. Because of the quantum confinement effect of CsPbX3 quantum dots, the absorption and photoluminescence (PL) emission peak were blue shifted to shorter wavelengths compare with bulk materials. Furthermore, this synthetic strategy provides a novel method in fabricating ultra-small photoluminescence quantum dots.

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