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Mechanical Characterization of Gypsum Composites Containing Inert and Insulation Materials from Construction and Demolition Waste and Further Application as A Gypsum Block.

ABSTRACT: This article analyzes the feasibility of using construction and demolition waste (expanded polystyrene, ceramic, and concrete waste) in a gypsum matrix to manufacture plaster for interior coatings or for prefabricated elements for interior partitions. To do this, several gypsum specimens were prepared (4 × 4 × 16 cm) incorporating different percentages of waste based on the weight of the gypsum (25%, 50%, and 75% of ceramic, concrete, and a mixture of both). Reference samples were also produced (without additions) to compare the results obtained. The compounds with the best performance were selected and lightened by preparing other samples in which 1/3 and 2/3 of the volume of ceramic, concrete, and mixed waste were replaced with expanded polystyrene (EPS). All samples were tested in the laboratory and the following physical and mechanical characteristics were determined: density, surface hardness, flexural strength, compressive strength, capillary water absorption, and thermal conductivity. Several applications were proposed for the selected compounds. A gypsum block with a sandwich configuration was obtained (40 × 20 × 10 cm) using the optimum compound. The block was further tested regarding its density and compression strength. A comparative analysis showed that it is possible to produce materials with a gypsum matrix by adding ceramic, concrete, and EPS waste, improving the behavior of the traditional gypsum and enabling them to be applied in various construction applications. These applications have a lower environmental impact than ordinary ones because they use less primary raw material, due to the reuse of waste.

SUBMITTER: Villoria Saez P

PROVIDER: S-EPMC6981795 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Mechanical Characterization of Gypsum Composites Containing Inert and Insulation Materials from Construction and Demolition Waste and Further Application as A Gypsum Block.

Villoria Sáez Paola P Del Río Merino Mercedes M Sorrentino Marica M Porras Amores César C Santa Cruz Astorqui Jaime J Viñas Arrebola Carmen C

Materials (Basel, Switzerland) 20200102 1

This article analyzes the feasibility of using construction and demolition waste (expanded polystyrene, ceramic, and concrete waste) in a gypsum matrix to manufacture plaster for interior coatings or for prefabricated elements for interior partitions. To do this, several gypsum specimens were prepared (4 × 4 × 16 cm) incorporating different percentages of waste based on the weight of the gypsum (25%, 50%, and 75% of ceramic, concrete, and a mixture of both). Reference samples were also produced ...[more]

PMID: 31906537

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Project description:Construction and demolition (C&D) waste is a novel, widespread environmental stress that negatively affects environment, organisms and ecosystem. Yet effects of cumulative consequences of C&D waste on the fitness and community structure of most underground insects remain unclear. With relatively sessile life underground lasting several years, cicadas can be an important aspect in forest nutrient cycles. Whether cicada nymphs are easily affected by C&D waste, and whether they have evolved any adaptations to cope with the adverse environments merit exploration. Here, we investigated the biodiversity, community structure, population dynamics and morphology of cicada nymphs in both uncontaminated and contaminated habitats by C&D waste in Guanzhong Plain, China since 2011. In total, 1,573 cicada nymphs were collected from 2011 to 2015, including 62 malformed nymphs. The malformed nymphs can be divided into three types: physically damaged individuals (still alive) (3.2%), fungus-infected individuals (dead) (64.5%), and bacterium-infected individuals (dead) (32.3%). The proportion of malformed nymphs increased year by year in the habitats contaminated by C&D waste. In the uncontaminated habitats, although no significant differences of population density among the investigated years were observed, yet there was a distinct increasing trend of population of Meimuna mongolica, whereas populations of both Cryptotympana atrata and Platypleura kaempferi distinctly decreased. This indicates that M. mongolica is possibly evolving into the most dominant species in the ecological niche when it competes with other sympatric species, but more researches are needed to establish whether there is a shift in the species composition of cicadas. In the habitats contaminated by C&D waste, a higher ratio of malformed individuals and a decline of population of both M. mongolica and C. atrata were revealed; P. kaempferi was not found in the contaminated habitats, indicating a weaker resistance of this species against C&D waste. The negative responses of cicada nymphs to C&D waste have significant implications for the habitat destruction. Cicada nymphs may be suitable bioindicators for underground-habitat-quality monitoring, as merits further research to reveal the association between the magnitude of C&D waste contamination with the fitness and population dynamics of cicada nymphs.

Project description:The aim of this study was to develop new sulfur-copolymer concrete composites using waste compounds that have good mechanical characteristics and show a resistance to biocorrosion. The comonomers used to synthesize the sulfur-organic copolymers were-90 wt. % sulfur; 5 wt. % dicyclopentadiene (DCPD); 5 wt. % organic monomers, styrene (SDS), 1-decene (SDD), turpentine (SDT), and furfural (SDF). The concrete composites based on sulfur-organic copolymers were filled with aggregates, sand, gravel, as well as additives and industrial waste such as fly ash or phosphogypsum. The sulfur-organic copolymers were found to be chemically stable (softening temperature, thermal stability, melting temperature, amount of recrystallized sulfur, and shore D hardness). Partial replacement of DCPD with other organic comonomers did not change the thermal stability markedly but did make the copolymers more elastic. However, the materials became significantly stiffer after repeated melting. All the tested copolymers were found to be resistant to microbial corrosion. The highest resistance was exhibited by the SDS-containing polymer, while the SDF polymer exhibited the greatest change due to the activity of the microorganisms (FTIR analysis and sulfur crystallization). The concrete composites with sulfur-organic copolymers containing DCPD, SDS, SDF, fly ash, and phosphogypsum were mechanically resistant to compression and stretching, had low water absorbance, and were resistant to factors, such as temperature and salt. Resistance to freezing and thawing (150 cycles) was not confirmed. The concrete composites with sulfur-organic copolymers showed resistance to bacterial growth and acid activity during 8 weeks of incubation with microorganisms. No significant structural changes were observed in the SDS composites after incubation with bacteria, whereas composites containing SDF showed slight changes (FTIR and microscopic analysis). The concrete composite containing sulfur, DCPD, SDS, sand, gravel, and fly ash was the most resistant to microbiological corrosion, based on the metabolic activity of the bacteria and the production of ergosterol by the molds after eight weeks of incubation. It was found that Thiobacillus thioparus was the first of the acidifying bacteria to colonize the sulfur concrete, decreasing the pH of the environment. The molds Penicillium chrysogenum, Aspergillus versicolor and Cladosporium herbarum were able to grow on the surface of the tested composites only in the presence of an organic carbon source (glucose). During incubation, they produced organic acids and acidified the environment. However, no morphological changes in the concretes were observed suggesting that sulfur-organic copolymers containing styrene could be used as engineering materials or be applied as binders in sulfur-concretes.

Dataset Information

Mechanical Characterization of Gypsum Composites Containing Inert and Insulation Materials from Construction and Demolition Waste and Further Application as A Gypsum Block.

Publications

Mechanical Characterization of Gypsum Composites Containing Inert and Insulation Materials from Construction and Demolition Waste and Further Application as A Gypsum Block.

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