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Degradation of dimethyl phthalate using persulfate activated by UV and ferrous ions: optimizing operational parameters mechanism and pathway.


ABSTRACT: The present study aimed to model and optimize the dimethyl phthalate (DMP) degradation from aqueous solution using UVC/ Na2S2O8/Fe2+ system based on the response surface methodology (RSM). A high removal efficiency (97%) and TOC reduction (64.2%) were obtained under optimum conditions i.e. contact time?=?90 min, SPS concentration?=?0.601 mM/L, Fe2+?=?0.075 mM/L, pH?=?11 and DMP concentration?=?5 mg/L. Quenching experiments confirmed that sulfate radicals were predominant radical species for DMP degradation. The effect of CO3 - on DMP degradation was more complicated than other aquatic background anions. The possible pathway for DMP decomposition was proposed according to HPLC and GC-MS analysis. The average oxidation state (AOS) and carbon oxidation state (COS) values as biodegradability indicators demonstrated that the UVC/SPS/Fe2+ system can improve the bioavailability of DMP over the time. Finally, the performance of UVC/SPS/Fe2+ system for DMP treatment in different aquatic solutions: tap water, surface runoff, treated and raw wastewater were found to be 95.7, 88.5, 80.5, and 56.4%, respectively. Graphical abstract.

SUBMITTER: Badi MY 

PROVIDER: S-EPMC6985424 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Degradation of dimethyl phthalate using persulfate activated by UV and ferrous ions: optimizing operational parameters mechanism and pathway.

Badi Mojtaba Yegane MY   Esrafili Ali A   Pasalari Hasan H   Kalantary Roshanak Rezaei RR   Ahmadi Ehsan E   Gholami Mitra M   Azari Ali A  

Journal of environmental health science & engineering 20190712 2


The present study aimed to model and optimize the dimethyl phthalate (DMP) degradation from aqueous solution using UV<sub>C</sub>/ Na<sub>2</sub>S<sub>2</sub>O<sub>8</sub>/Fe<sup>2+</sup> system based on the response surface methodology (RSM). A high removal efficiency (97%) and TOC reduction (64.2%) were obtained under optimum conditions i.e. contact time = 90 min, SPS concentration = 0.601 mM/L, Fe<sup>2+</sup> = 0.075 mM/L, pH = 11 and DMP concentration = 5 mg/L. Quenching experiments confirm  ...[more]

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