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Mn-Promoted Growth of Mg-Based Spinel and Pyroxene Nanostructures.


ABSTRACT: In this work, we demonstrate Mn-promoted growth of oxide nanostructures standing on a single-crystal MgAl2O4 substrate after heat treatment. Unlike the short truncated spinel pyramids under Au seeds, the addition of Mn produces spinel nanopillars with lengths of 100-300 nm and pyroxene nanowires up to 10 ?m. Compared to Au seeds, Au/Mn seeds have different adsorption behavior and therefore provide an additional mass transfer path along seed surfaces that promotes the growth of nanostructures. This vaporization approach has a potential of being applicable to a wide range of complicated oxides.

SUBMITTER: Lin M 

PROVIDER: S-EPMC6990621 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Mn-Promoted Growth of Mg-Based Spinel and Pyroxene Nanostructures.

Lin Minghui M   Liu Yushun Y   Zhu Guozhen G  

ACS omega 20200113 3


In this work, we demonstrate Mn-promoted growth of oxide nanostructures standing on a single-crystal MgAl<sub>2</sub>O<sub>4</sub> substrate after heat treatment. Unlike the short truncated spinel pyramids under Au seeds, the addition of Mn produces spinel nanopillars with lengths of 100-300 nm and pyroxene nanowires up to 10 μm. Compared to Au seeds, Au/Mn seeds have different adsorption behavior and therefore provide an additional mass transfer path along seed surfaces that promotes the growth  ...[more]

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