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Synthesis, characterization and application of crosslinked alginate as green packaging material.

ABSTRACT: Plastic films for food wrapping, packing are widely used due to their special properties. These fossil fuel derived films are associated with long degradation time, toxicity and environmental pollution. Pineapple waste, sea weed can be very good renewable, alternative carbon sources to produce edible films. These edible films can be consumed by lower animals thereby overcoming the disposal problems of accumulating waste plastic and hence reducing pollution. In the present study, crosslinked polymers are prepared from pectin (P)/sodium alginate (SA) through crosslinking with bio-based acids such as citric acid (CA) and tartaric acid (TA). Pectin was extracted from waste pineapple shell and sodium alginate extracted from seaweed. The crosslinked films were characterized by using various analytical techniques such as FT-IR, thermogravimetry, and scanning electron microscopy (SEM). Mice feed study (testing of edibility), plant growth substrate and vermicomposting of these films was studied. Finally a suitable application of these newly prepared polymeric films has been evaluated as wrapping material on food products such as chocolate and Indian vegetable puff to enhance the shelf life of food.

SUBMITTER: Singh P

PROVIDER: S-EPMC6992982 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Synthesis, characterization and application of crosslinked alginate as green packaging material.

Singh Pratiksha P Baisthakur Pankaj P Yemul Omprakash S OS

Heliyon 20200123 1

Plastic films for food wrapping, packing are widely used due to their special properties. These fossil fuel derived films are associated with long degradation time, toxicity and environmental pollution. Pineapple waste, sea weed can be very good renewable, alternative carbon sources to produce edible films. These edible films can be consumed by lower animals thereby overcoming the disposal problems of accumulating waste plastic and hence reducing pollution. In the present study, crosslinked poly ...[more]

PMID: 32021918

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Project description:Alginate hydrogels have been investigated for a broad variety of medical applications. The ability to assemble hydrogels at neutral pH and mild temperatures makes alginate a popular choice for the encapsulation and delivery of cells and proteins. Alginate has been studied extensively for the delivery of islets as a treatment for type 1 diabetes. However, poor stability of the encapsulation systems after implantation remains a challenge. In this paper, alginate was modified with 2-aminoethyl methacrylate hydrochloride (AEMA) to introduce groups that can be photoactivated to generate covalent bonds. This enabled formation of dual crosslinked structure upon exposure to ultraviolet light following initial ionic crosslinking into bead structures. The degree of methacrylation was varied and in vitro stability, long term swelling, and cell viability examined. At low levels of the methacrylation, the beads could be formed by first ionic crosslinks followed by exposure to ultraviolet light to generate covalent bonds. The methacrylated alginate resulted in more stable beads and cells were viable following encapsulation. Alginate microbeads, ionic (unmodified) and dual crosslinked, were implanted into a rat omentum pouch model. Implantation was performed with a local injection of 100?µl of 50?µg/ml of Lipopolysaccharide (LPS) to stimulate a robust inflammatory challenge in vivo. Implants were retrieved at 1 and 3?weeks for analysis. The unmodified alginate microbeads had all failed by week 1, whereas the dual-crosslinked alginate microbeads remained stable up through 3?weeks. The modified alginate microbeads may provide a more stable alternative to current alginate-based systems for cell encapsulation. STATEMENT OF SIGNIFICANCE:Alginate, a naturally occurring polysaccharide, has been used for cell encapsulation to prevent graft rejection of cell transplants for people with type I diabetes. Although some success has been observed in clinical trials, the lack of reproducibility and failure to reach insulin dependence for longer periods of time indicates the need for improvements in the procedure. A major requirement for the long-term function of alginate encapsulated cells is the mechanical stability of microcapsules. Insufficient mechanical integrity of the capsules can lead to immunological reactions in the recipients. In this work, alginate was modified to allow photoactivatable groups in order to allow formation of covalent crosslinks in addition to ionic crosslinking. The dual crosslinking design prevents capsule breakdown following implantation in vivo.

Project description:The contamination of water is increasing day by day due to the increase of urbanization and population. Textile industries contribute to this by discarding their waste directly into water streams without proper treatment. A recent study explores the treatment potential of copper oxide nanorods (CuO NRs) synthesized on a green basis in the presence of a biopolymer matrix of agar (AA) and alginate (Alg), in terms of cost effectiveness and environmental impact. The synthesized bio nanocomposite (BNC) was characterized by using different instrumental techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), ultra-violet spectroscopy (UV-Vis), scanning electron microscopy-energy dispersive X-ray-elemental analysis (SEM-EDX), transmission electron microscopy (TEM), selected area diffraction pattern (SAED) and X-ray photoelectron spectroscopy (XPS). The optical studies revealed that immobilization of CuO NRs with Alg-Agar biopolymer blend resulted in an increase in light absorption capacity by decreasing the energy bandgap from 2.53 eV to 2.37 eV. The bio nanocomposite was utilized as a photocatalyst for the degradation of amaranth (AN) dye from an aquatic environment under visible light irradiation. A statistical tool known as central composite design (CCD) associated with response surface methodology (RSM) was taken into consideration to evaluate the optimized values of process variables and their synergistic effect on photocatalytic efficiency. The optimized values of process variables were found to be irradiation time (45 min), AN concentration (80 ppm), catalyst dose (20 mg), and pH (4), resulting in 95.69% of dye degradation at 95% confidence level with desirability level 1. The rate of AN degradation was best defined by pseudo-first-order reaction based on the correlation coefficient value (R2 = 0.99) suggesting the establishment of adsorption-desorption equilibrium initially at the catalyst surface then photogenerated •O2- radicals interacting with AN molecule to mineralize them into small non-toxic entities like CO2, H2O. The material used has high efficiency and stability in photocatalytic degradation experiments up to four cycles of reusability.

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Synthesis, characterization and application of crosslinked alginate as green packaging material.

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Synthesis, characterization and application of crosslinked alginate as green packaging material.

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