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Planarization-Induced Activation Wavelength Red-Shift and Thermal Half-Life Acceleration in Hydrazone Photoswitches.

ABSTRACT: The optimization and modulation of the properties of photochromic compounds, such as their activation wavelengths and thermal relaxation half-lives (? _1/2), are essential for their adaptation in various applications. In this work, we studied the effect of co-planarization of the rotary fragment of two photochromic hydrazones with the core of the molecule on their switching properties. The Z and E isomers of both compounds exhibit red-shifted absorption bands relative to their twisted versions, allowing for their photoswitching using longer wavelengths of light. Additionally, the thermal half-lives of both hydrazones are drastically shortened from hundreds of years to days.

SUBMITTER: Shao B

PROVIDER: S-EPMC6996581 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Planarization-Induced Activation Wavelength Red-Shift and Thermal Half-Life Acceleration in Hydrazone Photoswitches.

Shao Baihao B Aprahamian Ivan I

ChemistryOpen 20200203 2

The optimization and modulation of the properties of photochromic compounds, such as their activation wavelengths and thermal relaxation half-lives (τ1/2), are essential for their adaptation in various applications. In this work, we studied the effect of co-planarization of the rotary fragment of two photochromic hydrazones with the core of the molecule on their switching properties. The Z and E isomers of both compounds exhibit red-shifted absorption bands relati ...[more]

PMID: 32025464

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