Ontology highlight
ABSTRACT:
SUBMITTER: Xie G
PROVIDER: S-EPMC7004126 | biostudies-literature | 2020 Jan
REPOSITORIES: biostudies-literature
Xie Gaozhan G Hauschild Miriam M Hoffmann Hendrik H Ahrens Lukas L Rominger Frank F Borkowski Michal M Marszalek Tomasz T Freudenberg Jan J Kivala Milan M Bunz Uwe H F UHF
Chemistry (Weinheim an der Bergstrasse, Germany) 20191216 4
The synthesis, property evaluation, and single crystal X-ray structures of four 5,7,12,14-tetrafunctionalized diazapentacenes are presented. The synthesis of these compounds either starts from tetrabromo-N,N-dihydrodiazapentacene or from a diazapentacene tetraketone. Pd-catalyzed coupling or addition of a lithium acetylide gave the precursors that furnish, after further redox reactions, the diazapentacenes as stable crystalline materials. The performance of the tetraphenyl-substituted compound a ...[more]