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Morphology-Directed Synthesis of LiFePO₄ and LiCoPO₄ from Nanostructured Li_{1+2 x}PO_{3+ x}.

ABSTRACT: A LiPO₃-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO₄ and LiCoPO₄, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.

SUBMITTER: El-Shinawi H

PROVIDER: S-EPMC7007206 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Morphology-Directed Synthesis of LiFePO4 and LiCoPO4 from Nanostructured Li1+2 xPO3+ x.

El-Shinawi Hany H Cussen Edmund J EJ Corr Serena A SA

Inorganic chemistry 20190508 10

A LiPO3-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO4 and LiCoPO4, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-i ...[more]

PMID: 31067037

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