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Identifying high-performance catalytic conditions for carbon dioxide reduction to dimethoxymethane by multivariate modelling.


ABSTRACT: In times of a warming climate due to excessive carbon dioxide production, catalytic conversion of carbon dioxide to formaldehyde is not only a process of great industrial interest, but it could also serve as a means for meeting our climate goals. Currently, formaldehyde is produced in an energetically unfavourable and atom-inefficient process. A much needed solution remains academically challenging. Here we present an algorithmic workflow to improve the ruthenium-catalysed transformation of carbon dioxide to the formaldehyde derivative dimethoxymethane. Catalytic processes are typically optimised by comprehensive screening of catalysts, substrates, reaction parameters and additives to enhance activity and selectivity. The common problem of the multidimensionality of the parameter space, leading to only incremental improvement in laborious physical investigations, was overcome by combining elements from machine learning, optimisation and experimental design, tripling the turnover number of 786 to 2761. The optimised conditions were then used in a new reaction setup tailored to the process parameters leading to a turnover number of 3874, exceeding by far those of known processes.

SUBMITTER: Siebert M 

PROVIDER: S-EPMC7012071 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Identifying high-performance catalytic conditions for carbon dioxide reduction to dimethoxymethane by multivariate modelling.

Siebert Max M   Krennrich Gerhard G   Seibicke Max M   Siegle Alexander F AF   Trapp Oliver O  

Chemical science 20191024 45


In times of a warming climate due to excessive carbon dioxide production, catalytic conversion of carbon dioxide to formaldehyde is not only a process of great industrial interest, but it could also serve as a means for meeting our climate goals. Currently, formaldehyde is produced in an energetically unfavourable and atom-inefficient process. A much needed solution remains academically challenging. Here we present an algorithmic workflow to improve the ruthenium-catalysed transformation of carb  ...[more]

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