Copolymerization of Propylene with Higher α-Olefins by a Pyridylamidohafnium Catalyst: An Effective Approach to Polypropylene-Based Elastomer.

ABSTRACT: In this contribution, we explored the copolymerization of propylene with higher α-olefins, including 1-octene (C8) 1-dodecene (C12), 1-hexadecene (C16) and 1-eicosene (C20), by using a dimethyl pyridylamidohafnium catalyst. A series of copolymers with varied comonomer incorporation, high molecular weight and narrow molecular weight distribution were obtained at mild conditions. The effects of the insertion of the comonomers on the microstructure, thermal and final mechanical properties were systemically studied by 13C NMR, wide-angle X-ray scattering, DSC and tensile test. Excellent mechanical performances were achieved by tuning the incorporation and chain length of the higher α-olefins. When the comonomer content reached above 12 mol.%, polypropylene-based elastomers were obtained with h

SUBMITTER: Yang F 

PROVIDER: S-EPMC7023639 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature