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Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water.


ABSTRACT: The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.

SUBMITTER: Ndiaye D 

PROVIDER: S-EPMC7024363 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water.

Ndiaye Daouda D   Coufourier Sébastien S   Mbaye Mbaye Diagne MD   Gaillard Sylvain S   Renaud Jean-Luc JL  

Molecules (Basel, Switzerland) 20200120 2


The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions. ...[more]

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