Nitrogen Incorporated Photoactive Brownmillerite Ca2Fe2O5 for Energy and Environmental Applications.
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ABSTRACT: Ca2Fe2O5 (CFO) is a potentially viable material for alternate energy applications. Incorporation of nitrogen in Ca2Fe2O5 (CFO-N) lattice modifies the optical and electronic properties to its advantage. Here, the electronic band structures of CFO and CFO-N were probed using Ultraviolet photoelectron spectroscopy (UPS) and UV-Visible spectroscopy. The optical bandgap of CFO reduces from 2.21?eV to 2.07?eV on post N incorporation along with a clear shift in the valence band of CFO indicating the occupation of N 2p levels over O 2p in the valence band. Similar effect is also observed in the bandgap of CFO, which is tailored upto 1.43?eV by N+ ion implantation. The theoretical bandgaps of CFO and CFO-N were also determined by using the Density functional theory (DFT) calculations. The photoactivity of these CFO and CFO-N was explored by organic effluent degradation under sunlight. The feasibility of utilizing CFO and CFO-N samples for energy storage applications were also investigated through specific capacitance measurements. The specific capacitance of CFO is found to increase to 224.67 Fg-1 upon N incorporation. CFO-N is thus found to exhibit superior optical, catalytic as well as supercapacitor properties over CFO expanding the scope of brownmillerites in energy and environmental applications.
SUBMITTER: Vavilapalli DS
PROVIDER: S-EPMC7026084 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
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