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Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer.


ABSTRACT: Functional materials displaying tunable emission and long-lived luminescence have recently emerged as a powerful tool for applications in information encryption, organic electronics and bioelectronics. Herein, we present a design strategy to achieve color-tunable ultralong organic room temperature phosphorescence (UOP) in polymers through radical multicomponent cross-linked copolymerization. Our experiments reveal that by changing the excitation wavelength from 254 to 370?nm, these polymers display multicolor luminescence spanning from blue to yellow with a long-lived lifetime of 1.2?s and a maximum phosphorescence quantum yield of 37.5% under ambient conditions. Moreover, we explore the application of these polymers in multilevel information encryption based on the color-tunable UOP property. This strategy paves the way for the development of multicolor bio-labels and smart luminescent materials with long-lived emission at room temperature.

SUBMITTER: Gu L 

PROVIDER: S-EPMC7029031 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer.

Gu Long L   Wu Hongwei H   Ma Huili H   Ye Wenpeng W   Jia Wenyong W   Wang He H   Chen Hongzhong H   Zhang Nan N   Wang Dongdong D   Qian Cheng C   An Zhongfu Z   Huang Wei W   Zhao Yanli Y  

Nature communications 20200218 1


Functional materials displaying tunable emission and long-lived luminescence have recently emerged as a powerful tool for applications in information encryption, organic electronics and bioelectronics. Herein, we present a design strategy to achieve color-tunable ultralong organic room temperature phosphorescence (UOP) in polymers through radical multicomponent cross-linked copolymerization. Our experiments reveal that by changing the excitation wavelength from 254 to 370 nm, these polymers disp  ...[more]

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