Dataset Information

Influence of Hydroxyl Groups on the Inhibitive Corrosion of Gemini Surfactant for Carbon Steel.

ABSTRACT: The corrosion inhibition performance of propanediyl-1,3-bis(N,N-dimethyl-N-dodecylammonium bromide) and propanediyl-1,3-bis(N,N-dihydroxyethyl-N-dodecylammonium bromide), abbreviated as PDDB and PDHDB, respectively, for carbon steel in 1.0 mol·L-1 hydrochloric acid solution was investigated using the gravimetric method and various electrochemical techniques, together with scanning electron microscopy and energy-dispersive spectrometry. Results show that PDHDB always has a better inhibition performance relative to PDDB, which can be attributed to the introduction of hydroxyl groups at the hydrophilic headgroups, thereby causing an extra interaction between inhibitors and the metal surface and favoring its adsorption. These findings highlight that the modification to the headgroups of Gemini-type inhibitors may be another effective approach to improving their inhibition performance.

SUBMITTER: Yin C

PROVIDER: S-EPMC7033669 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Influence of Hydroxyl Groups on the Inhibitive Corrosion of Gemini Surfactant for Carbon Steel.

Yin Chengxian C Kong Minjian M Zhang Juantao J Wang Yuan Y Ma Qingwei Q Chen Qibin Q Liu Honglai H

ACS omega 20200204 6

The corrosion inhibition performance of propanediyl-1,3-bis(N,N-dimethyl-N-dodecylammonium bromide) and propanediyl-1,3-bis(N,N-dihydroxyethyl-N-dodecylammonium bromide), abbreviated as PDDB and PDHDB, respectively, for carbon steel in 1.0 mol·L-1 hydrochloric acid solution was investigated using the gravimetric method and various electrochemical techniques, together with scanning electron microscopy and energy-dispersive spectrometry. Results ...[more]

PMID: 32095685

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Project description:Present work investigated the role of five different bacteria species as a corrosion inducer as well as corrosion inhibitor with carbon steel (CS). We observed the ability of different bacteria species on the metal surface attachment, biofilm formation, and determined Peroxidase, Catalase enzyme activity in the detached biofilm from the CS surface. We found that each strain has diverse conduct for surface attachment like DS1 3.3, DS2 2.5, DS3 4.3, DS4 4.0, and DS5 4.71 log cfu/cm2 and for biofilm 8.3 log cfu/cm2. The enzyme Peroxidase, Catalase was found in huge concentration inside the biofilm Peroxidase was maximum for DS4 36.0 U/ml and least for DS3 19.54 U/ml. Whereas, Catalase was highest for DS4, DS5 70.14 U/ml and least 57.2 U/ml for DS2. Scanning electron microscopy (SEM) was conducted to examine the biofilm and electrochemical impedance spectroscopy (EIS) were utilized to observe corrosion in the presence of bacteria. The electrochemical results confirmed that DS1, DS3, DS4, and DS5 strains have statistically significant MIC-factors (Microbially Influenced Corrosion) of 5.46, 8.51, 2.36, and 1.04, while DS2 protective effect factor of 0.89. Weight reduction results with carbon steel likewise supports that corrosion was initiated by DS1 and DS3, while DS2 and DS5 have no any impact though with DS4 we watched less weight reduction however assumed no role in the corrosion. We established the relation of Peroxidase enzyme activity of the isolates. DS1, DS3 and having Peroxidase in the range 22.18, 19.54 U/ml which induce the corrosion whereas DS2 and DS5 having 28.57 and 27.0 U/ml has no any effect and DS4 36 U/ml has inhibitory effect, increasing concentration inhibiting the corrosion. For Catalase DS1, DS3 have 67.28, 61.57 U/ml which induce corrosion while DS2 and DS5 57.71 and 59.14 U/ml also has no effect whereas DS4 70.14 U/ml can inhibit corrosion. Results clearly express that in a specific range both enzymes can induce the corrosion. Our goals are to pursuit and locate the potential role of the enzyme in corrosion induction and inhibition. There is still further work is proceeded for the more profound perception.

Dataset Information

Influence of Hydroxyl Groups on the Inhibitive Corrosion of Gemini Surfactant for Carbon Steel.

Publications

Influence of Hydroxyl Groups on the Inhibitive Corrosion of Gemini Surfactant for Carbon Steel.

Similar Datasets

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