Ontology highlight
ABSTRACT:
SUBMITTER: Dankhoff K
PROVIDER: S-EPMC7037042 | biostudies-literature | 2020 Jan
REPOSITORIES: biostudies-literature
Dankhoff Katja K Lochenie Charles C Weber Birgit B
Molecules (Basel, Switzerland) 20200129 3
Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N<sub>2</sub>O<sub>2</sub> Schiff base-like equatorial ligands and 4,4'-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordin ...[more]