Thermal Stability and Flame Retardancy of a Cured Trifunctional Epoxy Resin with the Synergistic Effects of Silicon/Titanium.

ABSTRACT: An amino curing agent containing silicon/titanium flame-retardant elements (STCA) based on (3-aminopropyl)triethoxysilane (APTES) and tetrabutyl titanate was successfully prepared. The thermal decomposition and flame-retardant properties of a STCA-cured trifunctional epoxy resin, which was facilely synthesized by 1,1,1-tris(4-hydroxyphenyl)ethane and epichlorohydrin via a two-step method, were compared with those of another amino curing agent containing silicon (SCA) based on APTES and methyltrimethoxysilane. The structures of STCA and SCA were characterized by Fourier transform infrared (FT-IR), ²⁹Si NMR, and Raman spectroscopies. The STCA-cured thermoset not only had good thermal stability with an initial decomposition temperature of 344.8 °C and a char yield of 52.7% at 800 °

SUBMITTER: Cheng Z 

PROVIDER: S-EPMC7057714 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature