Ontology highlight
ABSTRACT:
SUBMITTER: Fisher KJ
PROVIDER: S-EPMC7069233 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
Fisher Katherine J KJ Feuer Margalit L ML Lant Hannah M C HMC Mercado Brandon Q BQ Crabtree Robert H RH Brudvig Gary W GW
Chemical science 20200106 6
The high-valent nickel(iii) complex Ni(pyalk)<sub>2</sub> <sup>+</sup> (<b>2</b>) was prepared by oxidation of a nickel(ii) complex, Ni(pyalk)<sub>2</sub> (<b>1</b>) (pyalk = 2-pyridyl-2-propanoate). <b>2</b> and derivatives were fully characterized by mass spectrometry and X-ray crystallography. Electron paramagnetic resonance spectroscopy and X-ray photoelectron spectroscopy confirm that the oxidation is metal-centered. <b>2</b> was found to react with a variety of phenolic and hydrocarbon sub ...[more]