Solvent-controlled self-assembly of tetrapodal [4?+?4] phosphate organic molecular cage.
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ABSTRACT:
SUBMITTER: Feng GF
PROVIDER: S-EPMC7070053 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Publications
Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage.
Feng Gen-Feng GF Geng Jiao J Feng Fan-Da FD Huang Wei W
Scientific reports 20200313 1
Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO<sub>2</sub> adsorption over CH<sub>4</sub> is demonstrated by the gas adsorption experiment. ...[more]
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