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Fluorene-Based Donor-Acceptor Copolymers Containing Functionalized Benzotriazole Units: Tunable Emission and their Electrical Properties.


ABSTRACT: Monomers 4,7-dibromo-2H-benzo[d]1,2,3-triazole (m1) and 4,7-(bis(4-bromophenyl)ethynyl)-2H-benzo[d]1,2,3-triazole (m2) have been synthesized in good yields using different procedures. Monomers m1 and m2 have been employed for building new copolymers of fluorene derivatives by a Suzuki reaction under microwave irradiation using the same conditions. In each case different chain lengths have been achieved, while m1 gives rise to polymers for m2 oligomers have been obtained (with a number of monomer units lower than 7). Special interest has been paid to their photophysical properties due to excited state properties of these D-A units alternates, which have been investigated by density functional theory (DFT) calculations using two methods: (i) An oligomer approach and (ii) by periodic boundary conditions (PBC). It is highly remarkable the tunability of the photophysical properties as a function of the different monomer functionalization derived from 2H-benzo[d]1,2,3-triazole units. In fact, a strong modulation of the absorption and emission properties have been found by functionalizing the nitrogen N-2 of the benzotriazole units or by elongation of the ?-conjugated core with the introduction of alkynylphenyl groups. Furthermore, the charge transport properties of these newly synthesized macromolecules have been approached by their implementation in organic field-effect transistors (OFETs) in order to assess their potential as active materials in organic optoelectronics.

SUBMITTER: Torres-Moya I 

PROVIDER: S-EPMC7077272 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Fluorene-Based Donor-Acceptor Copolymers Containing Functionalized Benzotriazole Units: Tunable Emission and their Electrical Properties.

Torres-Moya Iván I   Vázquez-Guilló Rebeca R   Fernández-Palacios Sara S   Carrillo José Ramón JR   Díaz-Ortiz Ángel Á   Navarrete Juan Teodomiro López JTL   Ortiz Rocío Ponce RP   Delgado Mari Carmen Ruiz MCR   Mallavia Ricardo R   Prieto Pilar P  

Polymers 20200122 2


Monomers 4,7-dibromo-2<i>H</i>-benzo[<i>d</i>]1,2,3-triazole (<b>m1</b>) and 4,7-(bis(<i>4</i>-bromophenyl)ethynyl)-2<i>H</i>-benzo[<i>d</i>]1,2,3-triazole (<b>m2</b>) have been synthesized in good yields using different procedures. Monomers <b>m1</b> and <b>m2</b> have been employed for building new copolymers of fluorene derivatives by a Suzuki reaction under microwave irradiation using the same conditions. In each case different chain lengths have been achieved, while <b>m1</b> gives rise to  ...[more]

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