Dataset Information
Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand.
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ABSTRACT:
SUBMITTER: Schuhknecht D
PROVIDER: S-EPMC7079104 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Publications
Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand.
Chemistry (Weinheim an der Bergstrasse, Germany) 20200218 13
Potassium silanide [KSiH<sub>3</sub> ]<sub>∞</sub> contains 4.2 wt % of hydrogen and has been intensely studied as hydrogen storage material. The macrocyclic ligand Me<sub>4</sub> TACD (1,4,7,10-tetramethyl-1,4,7,10-tetraaminocyclododecane, L) stabilizes the full range of triphenylsilyl complexes [(L)MSiPh<sub>3</sub> ]<sub>n</sub> (M=Li-Cs), which react with H<sub>2</sub> or PhSiH<sub>3</sub> to form molecular [(L)MSiH<sub>3</sub> ]<sub>n</sub> that can be isolated in soluble form and fully cha ...[more]