Dataset Information

Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability.

ABSTRACT: Visible light-driving syntheses have emerged as a powerful tool for organic synthesis and for the preparation of macromolecules under mild and environmentally benign conditions. However, precious but nonreusable photosensitizers or photocatalysts are often required to activate the reaction, limiting its practicality. Here, it is reported that poly(1,4-diphenylbutadiyne) (PDPB) nanofibers exhibit remarkable activity in driving the living free radical polymerization under visible light. Moreover, PDPB nanofibers are very stable under irradiation of visible light and can be reused without appreciable loss of activity even after repeated cycling. The nanofiber will be a promising photocatalyst with excellent reusability and stability for the reactions driven by visible light.

SUBMITTER: Xia L

PROVIDER: S-EPMC7080551 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability.

Xia Lei L Cheng Bo-Fei BF Zeng Tian-You TY Nie Xuan X Chen Guang G Zhang Ze Z Zhang Wen-Jian WJ Hong Chun-Yan CY You Ye-Zi YZ

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20200127 6

Visible light-driving syntheses have emerged as a powerful tool for organic synthesis and for the preparation of macromolecules under mild and environmentally benign conditions. However, precious but nonreusable photosensitizers or photocatalysts are often required to activate the reaction, limiting its practicality. Here, it is reported that poly(1,4-diphenylbutadiyne) (PDPB) nanofibers exhibit remarkable activity in driving the living free radical polymerization under visible light. Moreover, ...[more]

PMID: 32195082

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Dataset Information

Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability.

Publications

Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability.

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