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Green synthesis of ZnO nanoparticles decorated on polyindole functionalized-MCNTs and used as anode material for enzymatic biofuel cell applications.

ABSTRACT: Presently, one of the most important aspects for the development of enzymatic biofuel cells (EBFCs) is to synthesize the novel electrode materials that possess high current density, low open-circuit voltage (OCV) and long-term stability. To achieve the above attributes, lots of new strategies are being used by the researchers for the development of advanced materials. Nowadays, nanomaterials and nanocomposites are the promising material that has been utilized as effective electrode material in solar cells, supercapacitors and biofuel cells application. Herein, we account for a novel electrocatalyst as electrode material that comprised ZnO nanoparticles decorated on the surface of polyindole (PIn)-multi-walled carbon nanotube (MWCNT), for the immobilization of glucose oxidase (GOx) enzyme and mediator (Ferritin). The PIn-MWCNT scaffold is prepared via in situ chemical oxidative polymerization of indole on the surface of MWCNT and assessed by myriad techniques. The micrograph of scanning electron microscopy (SEM) designated the interconnected morphology of MWCNTs in the polymer matrix. X-ray diffraction spectroscopy (XRD) and Fourier transform infrared spectroscopy (FTIR), confirm the crystallinity and different functional groups available in the synthesized material, respectively. The electrochemical assessment demonstrates that the ZnO/PIn-MWCNT/Frt/GOx nanobiocatalyst exhibits much higher electrocatalytic activity towards the oxidation of glucose with a maximum current density of 4.9?mA?cm-2 by consuming 50?mM glucose concentration in phosphate buffer saline (PBS) (pH 7.4) as the testing solution by applying 100 mVs-1 scan rates. The outcomes reflect that the as-prepared ZnO/PIn-MWCNTs/Frt/GOx biocomposite is a promising bioanode for the development of EBFCs.

SUBMITTER: Inamuddin

PROVIDER: S-EPMC7081323 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Green synthesis of ZnO nanoparticles decorated on polyindole functionalized-MCNTs and used as anode material for enzymatic biofuel cell applications.

Inamuddin Shakeel Nimra N Imran Ahamed Mohd M Kanchi Suvardhan S Abbas Kashmery Heba H

Scientific reports 20200319 1

Presently, one of the most important aspects for the development of enzymatic biofuel cells (EBFCs) is to synthesize the novel electrode materials that possess high current density, low open-circuit voltage (OCV) and long-term stability. To achieve the above attributes, lots of new strategies are being used by the researchers for the development of advanced materials. Nowadays, nanomaterials and nanocomposites are the promising material that has been utilized as effective electrode material in s ...[more]

PMID: 32193477

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Project description:The promising green synthesis of carbon dots (CDs) from microalga Chlorella pyrenoidosa was achieved using simple hydrothermal and microwave-assisted methods. Doping of nanomaterials by nonmetals (N, S, and P) was confirmed by X-ray photoelectron spectroscopy (XPS), while the existence of metals in the CDs was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and transmission electron microscopy (TEM), and Mg, Ca, K, and Na were found as the dominant doped metals. The novel nanomaterials with excellent photoluminescence (PL) properties were used for the modification of ZnO obtained by a simple hydrothermal process. In this regard, a series of ZnO decorated with multi-doped carbon dots (xCDs) was prepared and their photocatalytic properties were evaluated. The ZnO-xCD photocatalysts were characterized by various advanced techniques including X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), XPS, Brunauer-Emmett-Teller (BET), PL, ultraviolet-visible (UV-vis) spectroscopy and electrochemical impedance spectroscopy (EIS) analysis. The photocatalytic behaviour of the obtained materials was investigated in the degradation of carbamazepine (CBZ). The influence of the synthesis method of xCDs and their content on the activity of the photocatalyst was examined. The photocatalyst ZnO modified with 3% xCDs obtained by the microwave-assisted method revealed the highest effectiveness for CBZ degradation and allowed for a first-order degradation rate of 2.85 times in comparison with non-modified ZnO. The improvement of the photocatalytic process was achieved by support with peroxymonosulphate resulting in up to 3.18 times a first order kinetic rate constant compared with that of simple photocatalysis in the presence of ZnO-xCDs. Taken together, our synthesized multi-doped CDs and their nanohybrids with ZnO, can be considered as promising candidates for photocatalytic applications.

Dataset Information

Green synthesis of ZnO nanoparticles decorated on polyindole functionalized-MCNTs and used as anode material for enzymatic biofuel cell applications.

Publications

Green synthesis of ZnO nanoparticles decorated on polyindole functionalized-MCNTs and used as anode material for enzymatic biofuel cell applications.

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