High-resolution infrared action spectroscopy of the fundamental vibrational band of CN.

ABSTRACT: Rotational-vibrational transitions of the fundamental vibrational modes of the ¹²C¹⁴N⁺ and ¹²C¹⁵N⁺ cations have been observed for the first time using a cryogenic ion trap apparatus with an action spectroscopy scheme. The lines P(3) to R(3) of ¹²C¹⁴N⁺ and R(1) to R(3) of ¹²C¹⁵N⁺ have been measured, limited by the trap temperature of approximately 4 K and the restricted tuning range of the infrared laser. Spectroscopic parameters are presented for both isotopologues, with band origins at 2000.7587(1) and 1970.321(1) cm^-1, respectively, as well as an isotope independent fit combining the new and the literature data.

SUBMITTER: Domenech JL 

PROVIDER: S-EPMC7116308 | biostudies-literature | 2020 Nov-Dec

REPOSITORIES: biostudies-literature