Ontology highlight
ABSTRACT:
SUBMITTER: Sahoo SK
PROVIDER: S-EPMC7118168 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
Sahoo Sudhir K SK Heske Julian J Azadi Sam S Zhang Zhenzhe Z Tarakina Nadezda V NV Oschatz Martin M Khaliullin Rustam Z RZ Antonietti Markus M Kühne Thomas D TD
Scientific reports 20200402 1
The potassium salt of polyheptazine imide (K-PHI) is a promising photocatalyst for various chemical reactions. From powder X-ray diffraction data an idealized structural model of K-PHI has been derived. Using atomic coordinates of this model we defined an energetically optimized K-PHI structure, in which the K ions are present in the pore and between the PHI-planes. The distance between the anion framework and K<sup>+</sup> resembles a frustrated Lewis pair-like structure, which we denote as fru ...[more]