2-Methylimidazole Copper Iminodiacetates for the Adsorption of Oxygen and Catalytic Oxidation of Cyclohexane.

ABSTRACT: The mixed-ligand copper(II) iminodiacetates [Cu(ida)(2-mim)(H₂O)₂]·H₂O (1), [Cu(ida)(2-mim)₂]·2H₂O (2), [Cu(ida)(2-mim)(H₂O)]_n·4.5nH₂O (3), and [Cu₂(ida)₂(2-mim)₂]_n·nH₂O (4) (H₂ida = iminodiacetic acid, 2-mim = 2-methylimidazole) were obtained from neutral or alkaline solutions at different temperatures. The novel complex 4 contains very small holes with diameters of 2.9 Å, which can adsorb O₂ selectively and reversibly between 1.89 to 29.90 bars, compared with the different gases of N₂, H₂, CO₂, and CH₄. This complex is stable up to 150 °C based on thermal analyses and XRD patterns. The four complexes show catalytic activities that facilitate the conversion of cyclohexane to cyclohexanol and cyclohexanone with hydrogen peroxide in a solution. The total conversion is 31% for 4.

SUBMITTER: Chen X 

PROVIDER: S-EPMC7143979 | biostudies-literature |

REPOSITORIES: biostudies-literature