Ontology highlight
ABSTRACT:
SUBMITTER: Guðmundsson A
PROVIDER: S-EPMC7154773 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Guðmundsson Arnar A Schlipköter Kim Elisabeth KE Bäckvall Jan-E JE
Angewandte Chemie (International ed. in English) 20200219 13
We report the first Fe<sup>II</sup> -catalyzed biomimetic aerobic oxidation of alcohols. The principle of this oxidation, which involves several electron-transfer steps, is reminiscent of biological oxidation in the respiratory chain. The electron transfer from the alcohol to molecular oxygen occurs with the aid of three coupled catalytic redox systems, leading to a low-energy pathway. An iron transfer-hydrogenation complex was utilized as a substrate-selective dehydrogenation catalyst, along wi ...[more]